Null is one way to represent such a value, but it’s hardly the only.
Option-style algebraic types are another, and more or less strictly superior if working in a language with first class support for such, because they force you to explicitly handle the null/None/Empty/whatever case if you’re doing something with it that could fail (basically anything besides assignment or passing it along).
Seems beyond the simplicity TOML was aiming for. Absence is absence in the file, in your programming language you can wrap in whatever trickier you like or is relevant.