I've gotten pretty good at doing the reverse operation(given an RGB value, guess the color) because I'm red-green colorblind and that's how I figure out what color something is :)
jacobulus might have been referring to certain color spaces that are optimized for human use instead of for computer manipulation, such as HUSL (http://www.boronine.com/husl/). HUSL gives you a slider that actually changes the apparent brightness of a color to your eye: whereas HSL thinks that bright green is just as “light” as dark true blue, and HSV/HSB thinks that true blue is just as “bright” as white, HUSL colors with the same “lightness” actually do look equally light. Another human-optimized color space is CIELUV (https://en.wikipedia.org/wiki/CIELUV).