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I believe negative energy has been observed in tiny amounts in the Casimir Effect, no?



That's a misconception I've come across a few times. It creates a negative energy density relative to the ambient energy density, not an absolute negative value. In other words if you consider ambient energy density to be zero the. The casimit effect gives rise to negative energy densities, but if course zero point vacuum energy means the ambient energy density is never zero. The casimir effect cannot lead to 'true' negative energy densities.




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