The main reason there are more women is that women live longer. This also means that most of the "extra" women are over 70.
If you break the population down into age groups (e.g. 0-10, 10-20, etc.) most younger groups have more men than women. Combine this with the fact that younger women tend to pair up with older men, and you get more unattached men in the younger groups (but more unattached women in the older groups).
If you break the population down into age groups (e.g. 0-10, 10-20, etc.) most younger groups have more men than women. Combine this with the fact that younger women tend to pair up with older men, and you get more unattached men in the younger groups (but more unattached women in the older groups).