Does anyone know if the reason they performed the EVA during the night was to prevent overheating? The crew reported temperatures (presumably of the suit) of 33.8C during the EVAs.
I think the main factor might've been crew wakefulness.
Since they launched around the same time, I think their body clocks would've been tuned to that time too. They'd want all crew to be at the peak of their alertness in case of any emergency (particularly if they ended up having to deorbit in a hurry), so it might've been a significant factor in the timing.