No. The cores are not POWER10 at all. While there is a ton of microcode and interception magic happening (and nothing but the hypervisor, PR/SM IIRC, runs on metal - the hypervisor exposes partitions to the zVM environment) the cores are still very different from POWER and run their own s390x ISA.
You might be confusing it with the AS/400 CISC ISA, which exists as an emulation layer on top of POWER, since all IBMi machines are almost identical to their POWER counterparts.
There isn't an emulation layer for AS/400 though, it's native POWER code.
The AS/400 / 'i' are descendants of the System/38 and implement a "Technology Independent Machine Interface". Applications target this high-level interface, rather than the underlying hardware. Before first run (or when they're installed?) applications get compiled from abstract Machine Interface code to native code.
You might be confusing it with the AS/400 CISC ISA, which exists as an emulation layer on top of POWER, since all IBMi machines are almost identical to their POWER counterparts.