Not even close. CRC32 can easily run at >50GB/s single thread on this i7-12700K CPU (VPCLMULQDQ implementation). The BLAKE3 page claims around 7GB/s single thread. Fudging the figures a bit to cater to CPU differences, BLAKE3 is still a far cry from CRC32.
To be fair, it really depends on the platform. There's an argument to be made that platforms where you care about the difference are specifically the ones where BLAKE3 is slower (no SIMD, no threads).