I don't know if there's a "default" unit, but most people I interact with would use SI units (i.e. km, m, cm, mm, micron, nm, pm). Maybe more to your point, 630 nm is the same number of characters and a slightly more familiar unit. Writing a wavelength as 6300 angstroms is a bit like saying a marathon is 421,950 cm.
Anecdotally I've only really heard angstroms used in material science / condensed matter physics, where most small structures are small integer numbers of angstroms across.
Anyone else have this use of Ångström trigger an exception in their brain? The unit of default for wavelength is nm, not Å… (1nm=10Å)