The CRT acts like a capacitor, storing charge for quite considerable lengths of time. Consider that a B&W would typically run 10kV to 15kV, and color sets easily 25kV, and that should give you some idea of how much energy one of those things can hold. And with those kinds of voltages, you don't even need to make contact to find you've become a discharge path, that stuff will reach out and grab you across considerable air gaps.
