I. P(A and B) = P(A) P(B) {when independent}
II. P(A or B) = P(A) + P(B) {when mutually exclusive}
But in general:
III. P(A and B) = P(A) P(B|A)
IIII. P(A or B) = P(A) + P(B) - P(A and B)
The only way that I and II can both be true is that either P(A) = 0 or P(B) = 0. This does not imply though that A and B are mutual exclusive and independent, but it is a necessary condition. The conclusion is that if you're using both I and II, you're almost certainly doing something wrong.