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There is an ASTM standard: "ASTM C618 Standard Specification for Coal Fly Ash and Raw or Calcined Natural Pozzolan for Use in Concrete (AASHTO M 295)."[1]

Fly ash, like volcanic ash, is a pozzlanic ash. Both work in concrete. Fly ash is pulled out of the exhaust from a coal-fired power plant using electrostatic precipitators. Just like electrostatic air cleaners, but huge, they pull particles out of gases. So fly ash is cheap if there's a coal-fired power plant nearby. Convenient when there is no volcano handy.

There are downsides. The concrete takes longer to cure, which can hold up the next stage of construction. Curing in cold weather is difficult. The Romans didn't have that problem in their Mediterranean climate. Concrete curing requires some air in the mix, and fly ash, for some reason, tends to entrain less air than Portland cement.[2]

[1] https://www.cement.org/docs/default-source/fc_concrete_techn...

[2] https://www.fhwa.dot.gov/PAVEMENT/recycling/fach03.cfm




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