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A Bizarre Form of Water May Exist All over the Universe (2019) (wired.com)
147 points by arunbahl on Sept 6, 2021 | hide | past | favorite | 38 comments



Nautilus recently had a great article about this state of water in the context of our solar systems ice giants Neptune and Uranus: http://m.nautil.us/issue/102/hidden-truths/the-planets-with-... I think the line that really stood out to me is ‘in most of the universe rivers of water and coal are rare and ice XVIII and diamonds are common’


Diamonds are actually common here on earth too. The idea that they are rare is propaganda spread by the DeBeers cartel.


Diamonds are common in an economic sense, there's plenty to go around. But as far as planetary geology goes, diamond is a pretty small share of the crust. I suppose there may be large diamonds in the mantle, that would be cool to see.

But maybe it is similar across the galaxy, except for the odd moon-sized diamond here and there, a light dusting of micro-diamonds.


> there may be large diamonds in the mantle

Indeed:

https://gizmodo.com/is-the-earths-mantle-full-of-diamonds-18...


Superionic ice. See for details: https://www.nature.com/articles/s41586-019-1114-6



I just read "Black Ice" and it comes to my mind that William Gibson once more was way ahead of his time in 1984, writing "Neuromancer" ;)


> although it has never been seen until now, scientists think it might be among the most abundant forms of water in the universe.

Definitely top 10


2019


2019... so what?

Chemistry didn't change a lot in the last two years, thus such an article is as good as it had been published yesterday.


Standard procedure for titles


You've been active here for 9 years and haven't noticed yet that posts from previous years get a [year] tag in their title?


Sure I did, and that is fine when talking about the last fad in web programming.

But we don't need such nitpicking for articles on more stable arguments.


> Sure I did, and that is fine when talking about the last fad in web programming. But we don't need such nitpicking for articles on more stable arguments.

... right, that is the reason for putting the year in titles ...

Or maybe it's done so that you can quickly discern whether it's old news, or a new development of something you've heard about previously.


It isn't nitpicking, its just regular old helpful. Like, I want to see where you are coming from, but I'm actually kind of stuck on this. How is it nitpicking? Where I'm coming from is the expectation that a citation includes the year of publication.


Ice-nine?

Update: I originally wrote ice-9, which it turns out is ambiguous. I meant the one from Cat's Cradle.

https://en.wikipedia.org/wiki/Cat%27s_Cradle


Ice 18 - ice 9 irl is boring, unfortunately.


It’s funny that scientists actually thought an ice nine type situation had a minuscule but non-zero chance of occurring when they set off the first nuclear bomb: the entire atmosphere would ignite.


No, they didn't. They did calculations showing it was impossible, even with very generous assumptions of cross sections and physical processes (like cooling of the plasma by radiation). They would not have done the test if there was any chance that could have happened.


NOTE: I am not a physicist.

> They did calculations showing it was impossible

Doesn't mean they couldn't have been surprised by something their calculations didn't take into account. The yield for the Castle Bravo test in the 1950s was 2.5 times what was predicted [0], because some things they didn't take into account turned out to be important (namely that some of the material in the construction of the device would serve as additional fuel to the explosion).

For the first nuclear explosion in 1945, they were initiating an incredibly powerful chain reaction for the first time on Earth. To some extent you just gotta cross your fingers and hope that the chain reaction stops according to your predictions, because you don't know what the "unknown unknowns" are until you try it. The combination of "chain reaction" and "unknown unknowns" is frightening.

[0] https://en.wikipedia.org/wiki/Castle_Bravo


Yes they did. See the linked article below.

Note I said minuscule chance. That would be at the moment of detonating the bomb. If the assessment was earlier, the fact that they had to run calculations proves they considered it as a possibility.

It’s a strong claim to say they proved it couldn’t happen when they didn’t even know the bomb would work for sure.

I’m sure the bbc is hamming it up a bit, but the account of the scientist who freaked out when the bomb worked seems credible.

https://www.bbc.com/future/article/20210217-the-moments-that...

There, a source to back up the original statement. Got one that disproves it?

Some scientists believed it was a minuscule possibility at the time of the test, others didn’t believe it would happen. What was wrong about that statement?


Your source disproves it. That is, the BBC article links to https://sgp.fas.org/othergov/doe/lanl/docs1/00329010.pdf which says:

> It is shown that, whatever the temperature to which a section of the atmosphere may be heated, no self-propogating chain of nuclear reactions is likely to be started. The energy losses to radiation always overcompensate the gains due to the reactions.

It then goes on to point out that if considerably more powerful bombs (over 1,000 cubic meters in size) were exploded, then the energy losses to radiation isn't enough .. but that's okay because:

> energy transfer from electrons to light quanta by Compton scattering will provide a further safety factor and will make a chain reaction in air impossible.

That's about as definite as you can be that there would not be a possibility.

Note also the comment "the policy should be adopted of exaggerating the dangers at any point which appears at all questionable."

In the BBC article, "the scientist who freaked out" is the President of Harvard, right? From https://en.wikipedia.org/wiki/James_B._Conant he was a noted PhD chemist who was the chair of the National Defense Research Committee and present as a dignitary. He does not appear to be someone who understood the physics involved.

Additional, the BBC article quotes philosopher Toby Ord as saying "we were creating temperatures unprecedented in Earth's entire history".

This is bunk. Meteor Crater in Arizona had an impact energy of ~10 megatons - https://en.wikipedia.org/wiki/Meteor_Crater . The Chicxulub meteor was about a billion times greater - https://en.wikipedia.org/wiki/Chicxulub_crater#Impact_specif... .

Now, this is total heat, and the quote says "temperature". (Earthquakes release a lot of energy but over a large area, so the temperature isn't hot.)

Cosmic rays regularly hit the earth with much higher temperatures, like https://en.wikipedia.org/wiki/Oh-My-God_particle .

> there also was no evidence that any elected representative was told about the risk

Conant clearly had heard about this risk consideration. Why didn't he tell Roosevelt? Perhaps because no one thought it had even a minuscule chance of being possible?


Compton supposedly thought the odds were less than 1 in 3 million, see the addendum to this article. Aka minuscule but nonzero. Aka what I said if just one other of the hundreds of scientists thought that too.

Now go exhume those hundred their graves and do voodoo witchery go commune with the dead and get every other scientist involved to swear they didn’t entertain that belief. That’s the only way my statement could be shown to be wrong.

Sure the other main guys decided it was impossible but only after running calculations and later bomb tests proved it was not possible but neither of those things are what my comment said so please stop telling me those things.

I didn’t say all scientists or most scientists, I said “scientists” and it’s clear at least one involved scientists considered it a minuscule possibility. If commenters are so adamant at proving me wrong, they’ll have to prove no other scientists involved in the project, of the hundreds, considered it could happen.

https://blogs.scientificamerican.com/cross-check/bethe-telle...


This is from Perl S. Buck's interview with Compton. That's second-hand reporting from a non-scientist.

In your source, two sentences after the "less than 1 in 3 million" line, is:

> Dudley’s article provoked an exchange of letters in Bulletin of the Atomic Scientists and a response from Bethe, who said that Buck had “completely misunderstood” Compton and that there was “no chance whatever” that an atomic blast would “ignite the atmosphere.”

and ends with:

> Fear of atmospheric and oceanic ignition is a nightmare with "no relation to reality," he wrote.

Still, let's look at the stated facts.

Here's a copy of Buck's publication - http://large.stanford.edu/courses/2015/ph241/chung1/docs/buc... .

It says the 1 in 3 million calculation was done two years before the test.

Teller and Konopinski's report "Ignition of the Atmosphere With Nuclear Bombs" study, which concluded there was zero possibility, was written "before the first nuclear test at Alamogordo" - http://large.stanford.edu/courses/2015/ph241/chung1/ . Again, this report gives multiple reasons why an atmosphere chain reaction could not happen.

Based on the documents you've identified, it appears there was an early estimate that there might be a problem, but it was low enough for the project to continue. Later, a more detailed analysis shows there was no risk, and the tests occurred.

Recall that pfdietz's comment earlier was "They did calculations showing it was impossible. They would not have done the test if there was any chance that could have happened.".

You strongly asserted this was incorrect, and pointed to document in support of your view.

However, as I've pointed out, the documents appear to strongly support pfdietz's interpretation.

I want to know which involved scientist considered it a non-zero possibility in the last month or so before the Trinity test, after the Teller and Konopinski report had been circulated.

So far you haven't shown any. Conant wasn't involved in the science. Compton certainly was, but the evidence you've presented was from two years previous.

You can't disprove that some of those dead researchers were worried that setting off the bomb would wake dormant kaiju from the seabed. ;)


Let’s say you’re right for the sake of argument.

You agree that due to the consequences they were concerned enough to run the calcs even although they didn’t think it likely and they did this several years before the atomic bomb? For sake of argument, at the time of the bomb no scientist thought it was possible but a couple years before they did run calculations to verify the atmosphere would not ignite when the first bomb test was conducted.

That’s not incompatible with my very first statement. I’m not sure what the point of this debate is?


Your first statement was:

> "It’s funny that scientists actually thought an ice nine type situation had a minuscule but non-zero chance of occurring when they set off the first nuclear bomb:"

Note the "when they set off the first nuclear bomb".

This is not correct.


So let me summarize what this thread has been, it’s been a huge effort just to say, “no the comment is wrong because at the time they set it off they’d ruled out an ice nine situation because it was actually a couple years before exploding it that they considered the situation to be a serious enough concern when detonating the first nuclear bomb to actually run the calculations. The original comment was utterly wrong because it had the timeline goofed even although the main point about scientists considering an ice nine type scenario was accurate” (which was the main point, no the exact timing).

That’s this thread.

And my original statement has two reading because the “when” is ambiguous, and only one of those readings would be wrong if the first is assumed wrong for sake of argument.


This thread has been:

- you made a short and incorrect comment about timing

- pfdietz at https://news.ycombinator.com/item?id=28434032 made a short comment that you were wrong about the timing. (Note that pfdietz's comment is basically your summary of the thread.)

- you doubled-down by presenting information which you thought supported your viewpoint

- I pointed out that the documents did precisely the opposite

- You tripled down by presenting another document to support your viewpoint

- I pointed out that it still did not do that.

I don't know how "when they set off the first nuclear bomb" can be ambiguous. Had you written "before", yes, but "when"? No.

You also stated "It’s a strong claim to say they proved it couldn’t happen when they didn’t even know the bomb would work for sure.", which is hard to believe because you can read their proof yourself, and it was linked-to in your first reference.

In any case, your sources highlight how contentious this topic has been, which should make you realize how important it is to not being ambiguous about this topic.


“It’s funny that scientists actually thought an ice nine type situation had a minuscule but non-zero chance of occurring”

That without context doesn’t make any sense.

Adding “when they detonated the first nuclear bomb” tells when the ice nine situation could occur, when the scientists were still thinking that is not actually said.

This whole thread has been about people unhappy that “at one time” was left out as below.

“ It’s funny that [at one time] scientists actually thought an ice nine type situation had a minuscule but non-zero chance of occurring when they set off the first nuclear bomb: the entire atmosphere would ignite.”

Does adding in the implied “at one time” help you see the ambiguity?

Of course a thread will turn contentious when someone bluntly says “ No, they didn't.” when it’s a situation where they aren’t actually wrong about the main point.

Those reply comments come off needlessly aggressive when in reality if they thought the timing was off, the commenter could have said “yeah they did consider that ice nine situation but ruled it out a few years before the first test”. Instead they went on how “no they didn’t, it was impossible because xyz”


I was with you until that last sentence.


Here’s a bbc article that inspired my comment. That other response comment was wrong from the start.

https://www.bbc.com/future/article/20210217-the-moments-that...


This article claims that the substance conducts electricity through the movement of protons, but last I checked, protons have extremely strong bonds to the nucleus. Most substances conduct electrons. Anyone want to shed some light on whether the article's claim is actually true?

If so, are there other such substances that conduct electricity with protons? What is the electrical resistance of such substances? I feel it should be extremely high due to the increased mass of the protons.


First, this is an exotic material, so you should expect some weird stuff.

Second but probably more importantly you are correct that protons and neutrons are strongly bonded as part of a nucleus, what I think you are missing is that hydrogen molecules are essentially free-ranging protons and do not experience nuclear bonds with oxygen molecules as part of water, they are instead electrically bonded. It is not incorrect and even somewhat common to refer to hydrogen as being a proton, because typically it is. Sometimes you'll get heavier hydrogen with neutrons, but mostly you don't. Hydrogen also has a difficult time trapping and keeping electrons, so seeing it as a sort of 'hanger on' proton when its bonded is normal too.

I'm not aware of any thing that we humans use where a proton is the primary charge-carrier. I also won't speculate as to what sort of material properties they would have. If your thesis is 'protons as charge carriers is extremely unusual' then yes you would be correct. The reason that 'most substances conduct electrons' is because metals already conduct charge, which you are probably familiar with as the 'sea of electrons' theory, and semiconductors also use electrons or electron analogues as their charge carrier.

Does that answer your questions/doubts?



Oh super neat, thanks! If I understood correctly its more like a cation conductor than a specifically proton conductor, but much of the chemistry was beyond me.


> last I checked, protons have extremely strong bonds to the nucleus

according to the article:

> The oxygen atoms form a cubic lattice, but the hydrogen atoms spill free, flowing like a liquid through the rigid cage of oxygens

Hydrogen consists of a nucleus of just one proton.

> I feel [electrical resistance] should be extremely high

electrical resistance measures the opposition to a flow of current, whereas electrical reactance measures the opposition to a change in current.

If you are thinking about momentum, do you mean reactance?


I wonder if heavy water would also be able to turn into this form of ice. Would a nucleus of one proton and one neutron more through the lattice with the same ease? Would heavy superionic ice conduct electricity as well?


responding to:

> protons have extremely strong bonds to the nucleus

Protons are chemical shorthand for the H+ atomic ion. They are bound to the fluffy outer electron shells of oxygen atoms in water.

> If so, are there other such substances that conduct electricity with protons?

This is basically how the inside of some fuel cells work (note that there is a counter-flow, which is the "useful electricity" of electrons that travels OUTSIDE the fuel cell, but inside of the fuel cell the electricity flow is via H+)

https://en.wikipedia.org/wiki/Proton-exchange_membrane_fuel_...




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