Exactly; they got that out of their system with Windows RT. (And apparently the upcoming Windows 10 for ARM will ship with Win32 support via emulation.)
Win32 is an OS API, which doesn't necessarily relate to the CPU or other chipset members. Do you mean it will Win10 for ARM will support code targetted at ia32/amd64 CPUs via emulation?
In the event you are not joking, there are entire industries running on Win32. My industry alone (EDA) is a 100B dollar industry. I'm aware of many others.