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>Peak AC consumption is in the afternoon as people get home from work.

not really. The "duck" curve you're referring to is "net" load - ie. actual demand minus solar. The solar smooths/removes the midday peak (which in summer is significantly higher than the evening demand).

https://www.eia.gov/todayinenergy/detail.php?id=19111

Btw, the highest yearly peak loads all happened between 2pm and 5pm, including the all-time high record in 2006 at 14:44

http://www.caiso.com/Documents/CaliforniaISOPeakLoadHistory....




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