Plenty of places hotter than LA if it is the heat you are interested in. Adelaide had a heatwave a few years ago where it didn't drop below 35C for 10 nights straight, and had days over 46C.
LA certainly has more hours of sunlight, but it's not nearly as warm. However, hours of sunlight probably isn't what people mean when they say "sunnier", or else the Arctic would be a popular tourist destinations for "sun seekers" during its Summer.
LA and Sydney are natural comparisons, both are large cities with similar climates. Although I would argue that LA is drier (despite it raining both times I have visited).