Sure, but it's just as irresponsible (economically irrational) as an individual to go the other way.
Really, the "optimal" salary negotiation is for both the employer and the potential hire to first agree on a dollar-value of how much money the employee is expected to make the company—literally, what the hire is worth—and then, having come to agreement over that, to then negotiate what profit margin the company wants to keep of that created value.
You might recognize this as the process a hiring agency goes through to negotiate with an employer. In this case, the employee is their own hiring agency, and the one who will end up with the majority "cut."
Really, the "optimal" salary negotiation is for both the employer and the potential hire to first agree on a dollar-value of how much money the employee is expected to make the company—literally, what the hire is worth—and then, having come to agreement over that, to then negotiate what profit margin the company wants to keep of that created value.
You might recognize this as the process a hiring agency goes through to negotiate with an employer. In this case, the employee is their own hiring agency, and the one who will end up with the majority "cut."