Yes, I am aware of that but I wanted to understand the usage of 'look' at this point. It was a fault to try stuff using the .zshrc file at first because I ran into misunderstanding everything. It was just the first file that came in mind to me. Since sorting a source file and then "looking" for comments makes no sense in any way, grep seems to be really the better choice.
look "#" .zshrc
There are really a lot more comments (lines starting with '#') in my .zshrc then the first line.